Types of Fumigants

Chemical formula PH3
Odour Carbide or garlic-like
Boiling point 87.4°C
Freezing point -133.5°C
Molecular weight 34.04
Lowest explosion point 1.79% by volume in air
Solubility in water very slightly soluble
Method of evolution as fumigant From preparations of aluminium and magnesium phosphide
Pertinent chemical properties Reacts with copper and precious metals
Natural vapour pressure at different temperatures 0°C (32°F) 21.6 atmos20°C (68°F) 34.2 atmos 40°C (104°F) 51.9 atmos
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Methyl Bromide: monobromomethane

Chemical formula CH3Br
Odour Nil
Boiling point 3.6°C (38.5°F)
Freezing point -93°C
Molecular weight 94.95
Flammability limits in air Nonflammable
Solubility in water 1.34 g/100 ml at 25°C
Pertinent chemical properties Powerful solvent of organic materials, especially natural rubber. When pure, noncorrosive to metals. Liquid reacts with aluminium
Method of evolution as fumigant From steel cylinders under naturalor added pressure. Also dispensed from 1 lb cans or 20 ml glass ampoules
Commercial purity 99.4%
Natural vapour pressure at different temperatures 0°C (32°F) 690 mm10°C (50°F) 1006 mm
Hg 20°C (68°F) 1390 mm Hg
Hg 25°C (77°F) 1610 mm Hg
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